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Thermodynamic and Viscometric Evaluation of Biodiesel and Blends from Olive Oil and Cashew Nut Oil

Author Affiliations

  • 1Department of Petroleum Chemistry, School of Arts and Sciences, American University of NIGERIA
  • 2Lamido Zubairu Way, Yola By-Passs. P.M.B. 2250 Yola, Adamawa State, NIGERIA

Res.J.chem.sci., Volume 1, Issue (4), Pages 90-97, July,18 (2011)

Abstract

Biodiesel is a monoalkyl esters of long chain fatty acids derived from renewable feedstock like vegetable oils and animal fats. It is produced by transesterification in which oil or fat is reacted with a monohydric alcohol in the presence of a catalyst. In this research, transesterification process was used to convert olive oil and cashew nut oil into biodiesel (methyl ester). The selected material used in the preparation of this biodiesel was methanol, alkaline catalyst (KOH), constant temperature of 70o C at 1.5hrs, to optimize the experimental conditions for maximum biodiesel yield. The thermodynamic properties of the biodiesel produced such as heat content of the pure biodiesel (B100) and the blends were investigated.

References

  1. CIA., Central intelligence agency fleet alternative fuel use and vehicle acquisition report. The world fact book, available at http://www.cia.gov/cia/publication (2007)
  2. Hossain A.B., Nasrulhaq B.A., Salleh A. and Chandran S., Biodiesel Production from waste Soybean Oil Biomass as Renewable Energy and Environmental Recycled Process, African J. of Biotech, 9, 4233-4240 (2010)
  3. Tony P., Global Trends in Transport Fuels and the Role of Natural Gas, Sasol Chevron Australian Gas toLiquidsProject-http://aie.org.au/Content/NavigationMenu/PerthBranch/PastEvents (2003)
  4. Laguë C.M., Lo K.V and Staley L.M., Waste vegetable oil as a diesel fuel extender., Can. Agric. Eng., 30, 27-32 (1988)
  5. Mittelbach M. and Enzelsberger H., Transesterification of heated rapeseed oil for extending diesel fuel, JAOCS, 76, 545-550 (1999)
  6. Cankci M. and Van Gerpen., Biodiesel production via acid catalyst, Transactions of the American Society of Agric. Eng., 42, 1203-1210 (1999)
  7. Clark S.J., Anger L.W., Schrock M.D., Pinnaar P.G., Testing of alternate diesel fuel form tallow and soybean oil in Cummins N14 – 410 diesel engine. JAOCS61, 1632 – 1638, (1984)
  8. Ma F. and Hanna M., Biodiesel production – A review. Bioresource Tech70, 1 – 15, (1998)
  9. Tat M.E., Van Gerpen J.H. and Wang P.S., Fuel property effects on injection timing, ignition timing and oxides of nitrogen emissions from biodiesel-fueled engines, Ame. Soc. of Agric. Eng, 50, 1123–1128 (2007)
  10. Zhang Y., Dubé M.A. and McLean D.D. and Kates M., Biodiesel production from waste cooking oil: Process design and technological assessment, Bioresource Tech, 89, 1-6 (2003)
  11. Ullmann’s Encyclopedia of Technical Chemistry. 6th edn Electronic Release, Wiley-VCH; Bailey’s Industrial Oil & Fat Products, edited by Y.H.Hui, Wiley-Interscience, New York, (1996)
  12. Graboski M.S and Mc Cormick R.L., Combustion of fats and vegetable oil derived fuels in diesel engines, Progress in Energy and Comb. Sci, 24, 125 – 164 (1998)
  13. Altin R., Cetinkaya S. and Yucesu HS., Energy Converters, Mgt42, 529 – 538 (2001)
  14. Formo M.W., Physical properties of fats and fatty acids. Bailey’s Industrial Oil and Fat Products, 4th Edition., John Wiley and Sons, New York, Vol.1,(1979)
  15. Wang Y., Liu X., He H., Zhu S., Investigation of Biodiesel Production from Canola Oil using Mg-Al Hydrotalcite Catalysts. Cat. Comms, 8, 1107-1111 (2007)
  16. Chang D.Y., VanGerpen J.H., Lee I., Johnson L.A., Hammond E.G. and Marley S.J., Metathesis of methyl soyate with ruthenium catalysts, JAOCS73, 1549 – 1555 (1996)
  17. Reddy C.R., Oshel R. Verkade J.G., Room-temperature conversion of soybean oil and poultry fat to biodiesel catalysed by nanocrystalline calcium oxides, Energy Fuels20,1310-1314 (2006)
  18. Xie W., Peng H. and Chen L., Calcined Mg-Al Hydrotalcites as solid base catalyst for methanolysis of soybean oil, Journal of Mol. Cat., 246, 24-32 (2005)
  19. Yusuf N. and Sirajo, M., An experimental study of biodiesel synthesis from groundnut oil, Aus. J. Applied Sci., 3, 1623-1629 (2009)
  20. Knothe G. and Steidley K.R., Kinematic Viscosity of Biodiesel Fuel Components and Related Compounds, Fuel, 84, 1059-1065 (2005)
  21. Tat, M.E., Van G. and Jon H., The kinematic Viscosity of Biodiesel and its blend with Diesel Fuel. JAOCS, 12, 76, (1999)
  22. Van G.J., Shanks B. and Pruszko R., Biodiesel Analytical Methods, NREL Inc, Colorado, (2004)
  23. CAL2k., Isothermal bomb calorimeter. http://www.cal2k.com/article_4.asp
  24. Kegl B., Effects of biodiesel on emissions of a bus diesel engine, Bioresource Tech, 99, 863-873 (2008)